Would it dissolve?
Key Points
- A substance that can dissolve in water is soluble.
- A soluble, toxic substance spilled into the water could contaminate water intakes and the marine food web, if its concentration reaches a hazardous level. It also could harm marine animals or plants.
- The concentration of a dissolved substance is likely to be highest in small water bodies and/or places where there is little mixing by waves and currents.
- An insoluble substance doesn't dissolve in water. If spilled into the water and:
- It's denser than water, it will sink to the bottom. There, it can endanger bottom-dwelling animals (such as shellfish beds).
- It's less dense than water, it will float on the surface and can beach on shore. At the surface or on shore, it can endanger animals that spend time at the surface (such as seabirds and marine mammals).
- Check the substance's CAMEO 365betÓéÀÖ datasheet to find out about its water solubility .
Backgrounder
How a spilled hazardous substance could damage marine or aquatic life—or become a public health hazard—depends on its water solubility and its toxicity.
Water solubility is the maximum amount of a substance that can dissolve in water at a given temperature and pressure. Conditions that influence whether the maximum amount of a substance will dissolve and how long the process will take includeÌýtemperatureÌý(higher temperatures promote faster dissolving) andÌýmixingÌý(more stirring by waves or currents promotes faster dissolving).
Water solubility is shown as a percentage and also in other units (usually at 68°F). For example, the solubility of vinyl acetate in water is 2% (20 mg/mL or 20,000 mg/L). A solution of vinyl acetate in water can hold up to 2% vinyl acetate when the temperature is about 68°F. A substance that's completely soluble in water�100% can dissolve—is called miscible .
Whether a hazardous substance is water soluble affects how it can cause harm if spilled into a water body. Learn more about solubility and potential harm to marine animalsLearn more about solubility and potential harm to marine animals
Generally:
- An insoluble substance that is denser than water will sink to the bottom. There, it could harm bottom-dwelling marine animals. For example, it could smother shellfish beds.
- An insoluble substance that is less dense than water would float on the water surface and could beach on the shore. If it's toxic or flammable , its evaporating vapor could create a hazardous vapor cloud. A floating hazardous substance also could harm seabirds or marine mammals (as well as shore animals, if it were to beach).
- A soluble substance could form a plume in the water column. If it is toxic, it could contaminate water intakes or marine food webs, or injure marine animals.
Two factors influence how harmful a soluble hazardous substance could be in the water: dissolving rate and volume of water available. Learn more about these influencing factorsLearn more about these influencing factors
Dissolving rate: A substance that dissolves faster can reach higher concentrations in water than substances that dissolve more slowly. When dissolving takes less time, there's less time for waves and currents to disperse and dilute the dissolved substance. Higher concentrations of a hazardous substance are more likely to cause harm.
Some substances dissolve in a few seconds or minutes. Others require days or weeks. Water solubility doesn't directly tell you the rate at which the substance will dissolve in water, but generally:
- More soluble substances usually dissolve faster.
- Substances dissolve faster at higher temperatures.
- Substances dissolve faster where there's more mixing energy, such as areas of strong currents or wave action.
Volume of water available: In the ocean or a one of the Great Lakes, even a large volume of a toxic substance can be diluted down to harmless concentrations relatively quickly—especially if waves or currents contribute a lot of mixing energy. When a toxic substance is spilled into a small body of water (such as a canal or diked area), the concentration of the substance is more likely to reach a dangerous level, because less water is available to dilute the solution.
Besides these factors, consider a substance's toxicity when assessing its potential to harm marine life. Some substances with low solubilities can harm marine organisms because they also are toxic at low concentrations. DDT is an example: its solubility ranges from about 1�7 ppb , but it also is toxic to invertebrates at these low concentrations.
Water Solubility Information in CAMEO 365betÓéÀÖ
Follow the steps below to find out about a substance's solubility:
- Search for the chemical.
- In the Search Results pages, find the chemical datasheet, and click View Datasheet.
- Look in the Physical Properties section of the datasheet for the Water Solubility. Note that water solubility may be reported in different ways. See examples of water solubility valuesSee examples of water solubility values
Ìý - If the water solubility isn't listed in the Physical Properties section, look in theÌýGeneral Description in the Chemical Identifiers section of the datasheet. It often describes the chemical's behavior in water (e.g., "Mixes with water," "Sinks and mixes with water," or "Completely miscible with water").
Related Topics
- Will it react with water?
- Will it float or sink in water?
- Could it harm marine organisms?
- Would it produce dangerous vapor?
More Information Online
Ìý- Information on the standards and regulations for substances considered to be drinking water contaminants.