Is the RQ exceeded?
A Reportable Quantity (RQ) is a specific amount of either a hazardous substance specified in CERCLA or an Extremely Hazardous Substance (EHS) specified in EPCRA Section 302 (learn more about these federal regulations). If a chemical is released in amounts exceeding the RQ within a 24-hour period, specific notification requirements must be followed.
- CERCLA RQs: Facilities or vessels that release more than the RQ of a listed chemical within any 24-hour period must immediately report it to National Response Center (1-800-424-8802), as well as notifying the Local Emergency Planning Committee (LEPC) and the State Emergency Response Commission (SERC).
- EPCRA RQs: Any time an EHSÂ is released beyond the boundaries of a facility in an amount that exceeds the chemical's RQ, the owner or operator of the facility must immediately notify the LEPC and the SERC.
Finding an RQ and Checking Whether it's Exceeded
You can use CAMEO 365betÓéÀÖ to check whether there is an RQ for a substance on scene:
- Search for the chemical.
- In the Search Results pages, find the chemical datasheet, and click View Datasheet.
- Look in the Regulatory Information section of the datasheet for the CERCLA RQ data and the EPCRA 304 EHS RQ data from the EPA Consolidated List of Lists.
- Determine whether the RQ is exceeded by comparing the estimated release amount to the RQ. If the release amount is smaller, the release need not be reported under CERCLA or EPCRA. If the release amount is equal or larger, continue to step 5. See how to convert from gallons to pounds to compare the release amount to the RQSee how to convert from gallons to pounds to compare the release amount to the RQ
If the release amount is in gallons, you'll need to convert it to pounds to compare it to the RQ .
First, find the chemical's specific gravity (in the Physical Properties section of the datasheet). Then multiply that value by 8.32 (the weight of a gallon of water in pounds). The result is the density of the substance in pounds per gallon. Finally, multiply the number of gallons spilled by the density. This yields the weight in pounds of the release substance.
Here's an example:Â 15 gallons of chlorine has spilled. The chemical datasheet shows that the specific gravity is 1.424. Multiply 1.424 by 8.32 to get 11.85 pounds per gallon. Then multiply 11.85 pounds/gallon by 15 gallons to get 177.75 pounds of chlorine spilled.
- If the release duration is no more than 24 hours and the release amount is equal or larger than the RQ, the release must be reported. Continue to step 6 if the release duration is longer than 24 hours.
- If the release duration is longer than 24 hours, you need to determine the amount released during a 24-hour period and compare that to the RQ. See an example of calculating the amount released in 24 hoursSee an example of calculating the amount released in 24 hours
If the release has been at a continuous, steady rate for the entire time, you could estimate the 24-hour release amount by: (1)Â dividing 24 hours by the release duration in hours and then (2)Â multiplying that quantity by the release amount.
Here's an example of that calculation: The RQ for phosphorus trichloride is 1,000 pounds. Assume that 1,500 pounds of phosphorus trichloride was released at a continuous, steady rate over a 40-hour period. First, divide 24 hours by 40 hours to get 0.6. Then multiply 0.6 by 1500 pounds, which gives you 900 pounds released over 24 hours. Because 900 pounds is less than the RQ, the release does not need to be reported.
For More Information
 covers frequently asked questions about CERCLA RQs and EPCRA RQs.