NFPA Diamond
The NFPA 704 diamond (sometimes called the "fire diamond") is a standard placard used to quickly identify a chemical's level of hazard. If available, the NFPA diamond is shown in the Chemical Identifiers section of each chemical datasheet in CAMEO 365betÓéÀÖ.
The NFPA diamond is divided into 4 quadrants and the meaning of each code number and symbol is shown below:
- Within the blue, red, and yellow quadrants a number from 0 to 4 indicates the degree of risk associated with the chemical. The higher the number, the higher the risk.
- For some chemicals, the white quadrant contains symbols indicating special hazards.
The NFPA diamond is used at fixed locations (such as production facilities, warehouses, storage tanks, and storage sheds) and on some transported containers.
Interpreting NFPA Diamond Codes
Health Hazard (Blue Quadrant) CodesHealth Hazard (Blue Quadrant) Codes
The health hazard codes and their meanings are as follows:
- 4 = Materials that, under emergency conditions, can be lethal.
- 3 =Â Materials that, under emergency conditions, can cause serious or permanent injury.
- 2 =Â Materials that, under emergency conditions, can cause temporary incapacitation or residual injury.
- 1 =Â Materials that, under emergency conditions, can cause significant irritation.
- 0 =Â Materials that, under emergency conditions, would offer no hazard beyond that of ordinary combustible materials.
Flammability Hazard (Red Quadrant) CodesFlammability Hazard (Red Quadrant) Codes
The flammability hazard codes and their meanings are as follows:
- 4 = Materials that rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air and burn readily.
- 3 =Â Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials produce hazardous atmospheres with air under almost all ambient temperatures or, though unaffected by ambient temperatures, are readily ignited under almost all conditions.
- 2 =Â Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release vapor in sufficient quantities to produce hazardous atmospheres with air.
- 1 =Â Materials that must be preheated before ignition can occur. Materials require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur.
- 0 =Â Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand.
The instability (reactivity)Â hazard codes and their meanings are as follows:
- 4 = Materials that in themselves are readily capable of detonation or explosive decomposition or explosive reaction at normal temperatures and pressures.
- 3 =Â Materials that in themselves are capable of detonation or explosive decomposition or explosive reaction but that require a strong initiating source or must be heated under confinement before initiation.
- 2 =Â Materials that readily undergo violent chemical changes at elevated temperatures and pressures.
- 1 =Â Materials that in themselves are normally stable but that can become unstable at elevated temperatures and pressures.
- 0 =Â Materials that in themselves are normally stable, even under fire conditions.
Special Hazard (White Quadrant) CodesSpecial Hazard (White Quadrant) Codes
The special hazard codes and their meanings are as follows:
- W or "No water" = Materials that react violently or explosively with water. See topic on Could it react with water?
- OX or "Oxidizer" =Â Materials that possess oxidizing properties.
The NFPA diamond system is developed by the .