Reactivity Documentation
Acids, Strong Non-oxidizing |
| mixed with |
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Carbon Dioxide
- Hydrogen Sulfide
- Ammonia
Details
Acids, Strong Non-oxidizing
is a reactive group.
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Acids, Strong Non-oxidizing
mixed with
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
Thiocarbamates are hydrolyzed by acids with evolution of inert CO2 gas and toxic, flammable NH3 gas (Romanowski, F., H. Klenk. 2002. Thiocyanates and Isothiocyanates, Organic. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA. (Online)).
Thiocarbamates may release toxic and flammable H2S gas upon exposure to acids (Predicted by comparison to similar reactions).
Potential Gas Byproducts
- Carbon Dioxide (CO2)
- Hydrogen Sulfide (H2S)
- Ammonia (NH3)
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