Reactivity Documentation
Acids, Strong Non-oxidizing |
| mixed with |
Organometallics |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Carbon Monoxide
Details
Acids, Strong Non-oxidizing
is a reactive group.
Organometallics
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Acids, Strong Non-oxidizing
mixed with
Organometallics
Organometallics
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
Nickel tetracarbonyl reacts with acids to liberate toxic and flammable C=O gas (Atonsen, D.H., D.T. Meshri. 2005. Nickel Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. (Online))
Reaction of transition metal-alkyl compounds with non-oxidizing acids can lead to protonolysis of the compound and release of flammable hydrocarbon gases. For example, when dimethyl zirconocene, i.e. (C5H5)2 Zr (CH3)2, reacts with a tertiary ammonium compound (containing an [R3NH]+ cation), methane is released (Janiak, C. 2002. Metallocene Catalysts. Kirk-Othmer Encyclopedia of Chemical Technology. (Online)).
Potential Gas Byproducts
- Carbon Monoxide (CO)
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