Reactivity Documentation
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts |
| mixed with |
Metals, Alkali, Very Active |
Summary
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
-
May produce the following gases:
- Ammonia
Details
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
is a reactive group.
Metals, Alkali, Very Active
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
mixed with
Metals, Alkali, Very Active
Metals, Alkali, Very Active
Hazard Predictions
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
Thiocarbamate esters can be reduced by alkali metals at room temperature to thiocarbamate anions or to flammable amines and corrosive thiolates and alkoxides. Reactive radical intermediates are formed (A. G. M. Barrett, P. Prokopiou, D. Barton, Chem. Comm., 1979, p. 1175; A. G. M. Barrett, P. Prokopiou, D. Barton, R. B. Boar, J. F. McGhie, Chem. Comm., 1979, p. 1173).
Potential Gas Byproducts
- Ammonia (NH3)
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