Reactivity Documentation
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts |
| mixed with |
Hydrocarbons, Aliphatic Unsaturated |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Hydrogen Sulfide
Details
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
is a reactive group.
Hydrocarbons, Aliphatic Unsaturated
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
mixed with
Hydrocarbons, Aliphatic Unsaturated
Hydrocarbons, Aliphatic Unsaturated
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
Dithiocarbamate salts can react with acrylonitrile at ambient temperatures to form thiocarbamate esters or isocyanates, and toxic, flammable H2S gas. This reaction does not involve the nitrile moiety; rather it is a nucleophilic attack by the dithiocarbamate on the alkene portion of the acrylonitrile molecule. (Thorn, G.D., R.A. Ludwig. 1962. Dithiocarbamates and Related Compounds, Amsterdam: Elsevier. pp. 78-79).
Potential Gas Byproducts
- Hydrogen Sulfide (H2S)
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