Reactivity Documentation
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts |
| mixed with |
Acyl Halides, Sulfonyl Halides, and Chloroformates |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Alcohols
- Carbon Disulfide
Details
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
is a reactive group.
Acyl Halides, Sulfonyl Halides, and Chloroformates
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
mixed with
Acyl Halides, Sulfonyl Halides, and Chloroformates
Acyl Halides, Sulfonyl Halides, and Chloroformates
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
Dithiocarbamate salts can react with chloroformates (including phosgene and ethyl chloroformate) at ambient temperatures, forming isothiocyanates, alcohols, and the toxic, flammable gas carbonyl sulfide (Thorn, G.D., R.A. Ludwig. 1962. Dithiocarbamates and Related Compounds. Amsterdam: Elsevier. pp. 101, 104).
Potential Gas Byproducts
- Alcohols
- Carbon Disulfide (CS2)
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