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Hazard Predictions

• Flammable: Reaction products may be flammable
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)

Thiocarbonyl compounds can react with sulfur dichlorides ("Reactions of Thiocarbonyl Compounds with Chlorine and Sulfur Dichlorides," Organic Preparations and Procedures International: The New Journal for Organic Synthesis, Volume 17, Issue 4-5, 1985).

Thiocarbamates may release flammable and toxic carbonyl sulfide gas upon exposure to halogenating agents (Predicted). Caution should be used before proceeding. Further research of comparable examples in the literature or very small scale, carefully controlled experiments may be needed to fully assess compatibility. The generation of gases may be rather slow, however confinement may lead to dangerous conditions.

Potential Gas Byproducts

• Carbon Disulfide (CS2)