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Hazard Predictions

• Explosive: Reaction products may be explosive or sensitive to shock or friction
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive

BrF3 ignites or explodes on contact with most organic compounds, including halogenated organics (Mellor, J.W. 1941. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Volume 2. pp. 113; Mellor. 1956. Volume 2, Supplemental 1. pp. 164-167).

Fluorine reacts explosively with halocarbons, including carbon tetrachloride and chloroform (Mellor, J.W. 1956. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Volume 2, Supplemental 1. pp. 198).

CCl4 forms explosive mixtures with ClF3 at low temperatures (Mellor, J.W. 1956. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Volume 2, Supplemental 1. pp. 156).