Reactivity Documentation
Halogenated Organic Compounds |
| mixed with |
Amines, Phosphines, and Pyridines |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Halocarbons
Details
Reactivity Predictions (for each pair of reactive groups)
Halogenated Organic Compounds
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
Ethylenediamine reacts violently with ethylene chlorohydrin (Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 1554.).
Trimethylamine may react with RX compounds to form (CH2)NR and halogenated methanes (Rodd, E. H, Ed. Chemistry of Organic Compounds. New York: Elsevier Publishing Company, 1951. Vol. I pp. 380).
Aniline reacts vigorously with trichloromethane (Jackson, K.E. 1934. Chemical Reviews 14:269; Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 254).
The incompatibility of common halogenated hydrocarbons (CH2Cl2, CHCl3, etc.) with amines is a well-known reactivity issue in the chemical industry (Personal communication with industry experts).
Potential Gas Byproducts
- Halocarbons
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