Reactivity Documentation
Isocyanates and Isothiocyanates |
| mixed with |
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
-
May produce the following gases:
- Carbon Dioxide
Details
Isocyanates and Isothiocyanates
is a reactive group.
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
mixed with
Isocyanates and Isothiocyanates
Isocyanates and Isothiocyanates
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
Compounds containing P=O functionality catalyze decomposition of isocyanates to diimides, with evolution of CO2 gas (Six, C., F. Richter. 2003. Isocyanates, Organic. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmhH & Co. KGaA. (Online)).
Isocyanates may decompose in the presence of organic phosphates to liberate inert CO2 gas (Smith, P. A. S., Open-Chain Nitrogen Compounds, Vol. I. New York: W. A. Benjamin, Inc., 1965, pp. 243).
Potential Gas Byproducts
- Carbon Dioxide (CO2)
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