Reactivity Documentation
Isocyanates and Isothiocyanates |
| mixed with |
Peroxides, Organic |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Carbon Dioxide
- Carbonyl Sulfide
- Nitrogen Oxides
- Sulfur Dioxide
Details
Isocyanates and Isothiocyanates
is a reactive group.
Peroxides, Organic
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Isocyanates and Isothiocyanates
mixed with
Peroxides, Organic
Peroxides, Organic
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
Organic peroxides may explode on contact with thiocyanates (Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 2708.).
The reaction between isocyanates and organic peroxides may liberate toxic NOx, SO2, COS and inert CO2 gases (Predicted).
Potential Gas Byproducts
- Carbon Dioxide (CO2)
- Carbonyl Sulfide (COS)
- Nitrogen Oxides (NOx)
- Sulfur Dioxide (SO2)
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