Reactivity Documentation
Isocyanates and Isothiocyanates |
mixed with |
Sulfonates, Phosphonates, and Thiophosphonates, Organic |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
-
May produce the following gases:
- Carbon Dioxide
Details
Isocyanates and Isothiocyanates
is a reactive group.
Sulfonates, Phosphonates, and Thiophosphonates, Organic
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Isocyanates and Isothiocyanates
mixed with
Sulfonates, Phosphonates, and Thiophosphonates, Organic
Sulfonates, Phosphonates, and Thiophosphonates, Organic
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
Compounds containing P=O functionality catalyze decomposition of isocyanates to diimides, with evolution of innocuous CO2 gas (Six, C., F. Richter. 2003. Isocyanates, Organic. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmhH & Co. KGaA).
Isocyanates may decompose in the presence of organic phosphates to liberate inert CO2 gas (Smith, P. A. S., Open-Chain Nitrogen Compounds, Vol. I. New York: W. A. Benjamin, Inc., 1965, pp. 243).
Potential Gas Byproducts
- Carbon Dioxide (CO2)