Reactivity Documentation
Isocyanates and Isothiocyanates |
mixed with |
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
Summary
- Flammable: Reaction products may be flammable
- Toxic: Reaction products may be toxic
Details
Isocyanates and Isothiocyanates
is a reactive group.
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Isocyanates and Isothiocyanates
mixed with
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Hazard Predictions
- Flammable: Reaction products may be flammable
- Toxic: Reaction products may be toxic
Isocyanates and isothiocyanates can be reduced to amines with metal hydrides (Cartolano, A. R. and Vedage, G. A. 2004. Amines by Reduction. Kirk-Othmer Encyclopedia of Chemical Technology. (Online); Kammermeier, B. 2000. Reduction. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).
Isocyanates can be reduced to formamides with lithium aluminum tri-tert-butoxide (Kammermeier, B. 2000. Reduction. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).