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Hazard Predictions

• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
• Polymerization hazard: Polymerization reaction may become intense and may cause pressurization

The combination of isocyanates or thioisocyanates with anilines are expected to result in reactions similar to those between isocyanates with amines. We provide the following as examples:

Isocyanates polymerize readily, particularly with amines (Richter, R.H., R.D. Priester Jr. 2000. Isocyanates, Organic. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc.).

Triethylphosphine may cause polymerization of isocyanates (Pohanish, Richard P.; Greene, Stanley A. (2009). Wiley Guide to Chemical Incompatibilities (3rd Edition). John Wiley & Sons).

Isocyanates undergo violent, rapid reactions with amines (Pohanish, Richard P.; Greene, Stanley A. (2009). Wiley Guide to Chemical Incompatibilities (3rd Edition). John Wiley & Sons).