Reactivity Documentation
Acids, Strong Oxidizing |
| mixed with |
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Carbon Dioxide
- Hydrogen Sulfide
- Ammonia
- Nitrogen Oxides
- Sulfur Dioxide
Details
Acids, Strong Oxidizing
is a reactive group.
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Acids, Strong Oxidizing
mixed with
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
Thiocarbamates are hydrolyzed by acids with evolution of inert CO2 gas and toxic, flammable NH3 gas (Romanowski, F., H. Klenk. 2002. Thiocyanates and Isothiocyanates, Organic. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA. (Online)).
Oxidizing acids may react with thiocarbamates to liberate toxic SO2, H2S, and NOx gases and inert CO2 gas (Predicted).
Potential Gas Byproducts
- Carbon Dioxide (CO2)
- Hydrogen Sulfide (H2S)
- Ammonia (NH3)
- Nitrogen Oxides (NOx)
- Sulfur Dioxide (SO2)
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