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Hazard Predictions

• Flammable: Reaction products may be flammable
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive

Hydrides react spontaneously and irreversibly with proton donors, including inorganic oxidizing acids, evolving flammable H2 gas (Rittmeyer, P., U. Wietelmann 2002. Hydrides. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA. (Online)).

Diphenyldistibene (PhSb=SbPh) is explosively oxidized by nitric acid (Schmidt, H., Justus Liebigs Annalen der Chemie, 1920, 421, 235).

NaBH4 may ignite on contact with H2SO4 (Pascal, P. 1961. Nouveau Trait茅 de Chimie Min茅rale. Vol. 6, p. 337. Masson et Cie.).

HNO3 reacts violently with diphenylmercury, even at low temperatures (Whitmore, F. C., 1921, Organic Compounds of Mercury, New York, Chemical Catalog Co. Inc., p. 168).

Cesium acetylide explodes on contact with nitric acid (J. W. Mellor, 1946. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 5, pp. 848. Longmans, Green and Co Ltd.).

Potential Gas Byproducts

• Hydrogen (H2)