Reactivity Documentation
Sulfides, Organic |
| mixed with |
Metals, Elemental and Powder, Active |
Summary
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
-
May produce the following gases:
- Hydrogen
Details
Sulfides, Organic
is a reactive group.
Metals, Elemental and Powder, Active
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Sulfides, Organic
mixed with
Metals, Elemental and Powder, Active
Metals, Elemental and Powder, Active
Hazard Predictions
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
Alkali and alkali earth metals perform one-electron reductions of thioethers, producing corrosive metal thiolates and metal alkyls. In the presence of proton sources, thiols and alkanes are produced (E. M. Kaiser, Synthesis, 1972, (8), p. 391-415).
Reactions of alkali or alkali earth metals and thiols produce flammable H2 gas and corrosive metal thiolates (W.C. Fernelius and G.W. Watt, Chem. Rev. 1937, 20, p. 195-258).
Potential Gas Byproducts
- Hydrogen (H2)
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