Reactivity Documentation
Sulfides, Organic |
mixed with |
Acyl Halides, Sulfonyl Halides, and Chloroformates |
Summary
- Corrosive: Reaction products may be corrosive
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Acid Fumes
- Hydrogen Chloride
- Hydrogen Halide
Details
Sulfides, Organic
is a reactive group.
Acyl Halides, Sulfonyl Halides, and Chloroformates
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Sulfides, Organic
mixed with
Acyl Halides, Sulfonyl Halides, and Chloroformates
Acyl Halides, Sulfonyl Halides, and Chloroformates
Hazard Predictions
- Corrosive: Reaction products may be corrosive
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
Acetyl chloride reacts with thiols to form thioesters, releasing toxic HCl gas as a byproduct (Wagner, F.S., Jr. 2005. Acetyl Chloride. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. (Online)).
Potential Gas Byproducts
- Hydrogen Chloride (HCl)
- Hydrogen Halide (HX)
- Acid Fumes