Reactivity Documentation
Sulfides, Organic |
| mixed with |
Azo, Diazo, Azido, Hydrazine, and Azide Compounds |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
-
May produce the following gases:
- Carbon Dioxide
- Nitrogen
Details
Sulfides, Organic
is a reactive group.
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
mixed with
Sulfides, Organic
Sulfides, Organic
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Addition of dry benzenediazonium chloride to crude liquid HSSSH caused an explosively violent interaction (King, W.B. et. al., J. Amer. Chem. Soc., 1932, 54, 3073).
Aryl azides may react with organic sulfides to liberate inert CO2 gas (Smith, P. A. S., Open-Chain Nitrogen Compounds, Vol. I. New York: W. A. Benjamin, Inc., 1965, pp. 333).
Azo compounds may react with organic sulfides to liberate inert N2 gas (Predicted).
Potential Gas Byproducts
- Carbon Dioxide (CO2)
- Nitrogen (N2)
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