Reactivity Documentation
Metals, Elemental and Powder, Active |
| mixed with |
Sulfonates, Phosphonates, and Thiophosphonates, Organic |
Summary
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
-
May produce the following gases:
- Hydrocarbons
- Sulfur Dioxide
Details
Metals, Elemental and Powder, Active
is a reactive group.
Sulfonates, Phosphonates, and Thiophosphonates, Organic
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Metals, Elemental and Powder, Active
mixed with
Sulfonates, Phosphonates, and Thiophosphonates, Organic
Sulfonates, Phosphonates, and Thiophosphonates, Organic
Hazard Predictions
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
The sulfonyl (-SO2-) group can be eliminated from sulfones by reducing agents such as aluminum amalgam (Roy, K.-M. 2000. Sulfones and Sulfoxides. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).
Sulfones are cleaved by alkali and alkali earth metals to form metal sulfinate salts and highly basic metal alkyls. In the presence of proton sources, alkanes are produced (E. M. Kaiser, Synthesis, 1972, (8), p. 391-415).
Potential Gas Byproducts
- Hydrocarbons
- Sulfur Dioxide (SO2)
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