Reactivity Documentation
Nitriles |
mixed with |
Metals, Elemental and Powder, Active |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Polymerization hazard: Polymerization reaction may become intense and may cause pressurization
-
May produce the following gases:
- Ammonia
Details
Nitriles
is a reactive group.
Metals, Elemental and Powder, Active
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Metals, Elemental and Powder, Active
mixed with
Nitriles
Nitriles
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Polymerization hazard: Polymerization reaction may become intense and may cause pressurization
Nitriles can be reduced by alkali metal amalgams, forming reactive radical intermediates. In the presence of a proton source, amines are produced (Cartolano, A. R. and Vedage, G. A. 2004. Amines by Reduction. Kirk-Othmer Encyclopedia of Chemical Technology. (Online)).
Rapid polymerization of acrylonitrile can be initiated by free radicals, such as alkali or alkali earth metals (Bradzil, J. F. 2010. Acrylonitrile. Kirk-Othmer Encyclopedia of Chemical Technology. (Online)).
Potential Gas Byproducts
- Ammonia (NH3)