Reactivity Documentation
Peroxides, Organic |
| mixed with |
Acyl Halides, Sulfonyl Halides, and Chloroformates |
Summary
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Acid Fumes
- Hydrogen Chloride
- Hydrogen Halide
- Sulfur Dioxide
Details
Peroxides, Organic
is a reactive group.
Acyl Halides, Sulfonyl Halides, and Chloroformates
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Peroxides, Organic
mixed with
Acyl Halides, Sulfonyl Halides, and Chloroformates
Acyl Halides, Sulfonyl Halides, and Chloroformates
Hazard Predictions
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
Peroxyacids form peroxyesters with acyl halides, evolving toxic acid gases (e.g., HCl) (Klenk, H., P.H. Gotz, R. Siegmeier, and W. Mayr. 2002. Peroxy Compounds, Organic. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA. (Online)).
Mixtures of dibenzoyl peroxide and acyl halides are impact-sensitive explosives (Sekida, O. 1974. Jap. Pat. 40:220).
Diphenyl peroxide reacts with thionyl chloride to liberate toxic SO2 and HCl gases (Hawkins, E. G. E. Organic Peroxides. New York: Van Nostrand, 1961, pp. 327).
Potential Gas Byproducts
- Hydrogen Chloride (HCl)
- Hydrogen Halide (HX)
- Sulfur Dioxide (SO2)
- Acid Fumes
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