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Hazard Predictions

• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive

Organic peroxides may decompose to liberate toxic and flammable alcohol and ether, flammable hydrocarbon and inert CO2 gases upon exposure to chlorosilanes and halogenating agents; additionally, toxic and flammable Cl2 and ClO2 gases may be generated (Predicted).

Benzoyl peroxide undergoes a thermal decomposition to CO2, BzOH, benzene and other hydrocarbons, and diphenyl ether (Uetake et al., Chem. Abs. 1974. 81 5175). O2 gas may also be released from the decomposition of organic peroxides (Davies, A. G. Organic Peroxides. London: Butterworths, 1961. pp. 171).

Some peroxides may liberate aldehydes upon decomposition, such as dimethyl peroxide which gives formaldehyde upon decomposition (Rodd, E. H, Ed. Chemistry of Organic Compounds. New York: Elsevier Publishing Company, 1951. Vol. Ia pp. 327).

Potential Gas Byproducts

• Oxygen (O2)
• Halogen Gas (X2)
• Halogen Oxides (XO2)