Reactivity Documentation
Sulfonates, Phosphonates, and Thiophosphonates, Organic |
| mixed with |
Nitrides, Phosphides, Carbides, and Silicides |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Hydrogen
- Hydrocarbons
- Sulfur Dioxide
Details
Sulfonates, Phosphonates, and Thiophosphonates, Organic
is a reactive group.
Nitrides, Phosphides, Carbides, and Silicides
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Sulfonates, Phosphonates, and Thiophosphonates, Organic
mixed with
Nitrides, Phosphides, Carbides, and Silicides
Nitrides, Phosphides, Carbides, and Silicides
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
Sulfones with alpha-hydrogen atoms can be deprotonated by strong anionic bases such as Grignard reagents, sodium hydride, or butyllithium, with evolution of flammable hydrogen or hydrocarbon gases, and possible evolution of toxic sulfur dioxide gas (Roy, K.-M. 2000. Sulfones and Sulfoxides. Ullmann's Encyclopedia of Industrial Chemistry. (Online)). Nitrides, phosphides, carbides, and silicides are also strong anionic bases and may react in a similar way.
Potential Gas Byproducts
- Hydrogen (H2)
- Hydrocarbons
- Sulfur Dioxide (SO2)
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