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Hazard Predictions

• Flammable: Reaction products may be flammable
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive

NaOH reacts explosively with NaBH4 at elevated temperatures, with evolution of flammable hydrogen gas (Mikheeva, V.I. et al. 1969. Chemical Abstracts 71:85064).

The product of the reaction between phenyllithium and titanium tetraethoxide is air- and water-sensitive (Gilman, H. et al., J. Org. Chem., 1945, 10, 507).

Silane reacts with aqueous solutions of strong bases to form hydrogen and silicates (Eggeman, T. 2001. Hydrides. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. (Online)).

Potential Gas Byproducts

• Hydrogen (H2)