Reactivity Documentation
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
| mixed with |
Cyanides, Inorganic |
Summary
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Hydrogen
Details
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
is a reactive group.
Cyanides, Inorganic
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Cyanides, Inorganic
mixed with
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Hazard Predictions
- Corrosive: Reaction products may be corrosive
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
Sodium borohydride reacts with hydrogen cyanide to form the extremely toxic reducing agent sodium cyanoborohydride (NaBH3CN) and flammable H2 gas (Eggeman, T. 2001. Hydrides. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. (Online)).
Sodium cyanide reacts with borane in THF to form the extremely toxic reducing agent sodium cyanoborohydride (NaBH3CN) (Rittmeyer, P., U. Wietelmann. 2002. Hydrides. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA. (Online)).
Potential Gas Byproducts
- Hydrogen (H2)
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