Reactivity Documentation
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
| mixed with |
Fluoride Salts, Soluble |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
-
May produce the following gases:
- Hydrogen
- Hydrogen Fluoride
Details
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
is a reactive group.
Fluoride Salts, Soluble
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
mixed with
Fluoride Salts, Soluble
Fluoride Salts, Soluble
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
No evidence of an adverse reaction was found for the case where both the fluoride salt and the metal hydride are free from water. However, if water is present, the fluoride salt could react to form a small amount of hydrofluoric acid. Hydrides react spontaneously and irreversibly with proton donors such as acids to form flammable H2 gas (Rittmeyer, P., U. Wietelmann. 2002. Hydrides. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA. (Online); Eggeman, T. 2001. Hydrides. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. (Online)).
Potential Gas Byproducts
- Hydrogen (H2)
- Hydrogen Fluoride (HF)
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