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Reactivity Documentation

Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes

mixed with

Siloxanes

Summary

Details

Siloxanes is a reactive group.

Reactivity Predictions (for each pair of reactive groups)

Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes mixed with
Siloxanes

Hazard Predictions

Disiloxane can be cleaved and reduced to toxic silane gas at temperatures as low as -33C by metal hydrides including lithium aluminum hydride, sodium borohydride, lithium borohydride and sodium hydride (Schumb, Walter C. and Robinson, Dean W. 1955. J. Am. Chem. Soc. 77 (20), pp 5294-5294).

Lithium hydride reacts vigorously with silicates when heated above 180 C (Sullivan, E. and Wade, R. 1980. Hydrides. Kirk-Othmer Encyclopedia of Chemical Technology, 3rd ed. John Wiley & Sons, Inc.).

Potential Gas Byproducts