Reactivity Documentation
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
| mixed with |
Halogenating Agents |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
-
May produce the following gases:
- Hydrogen
Details
Reactivity Predictions (for each pair of reactive groups)
Halogenating Agents
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
The reaction of lithium aluminum hydride (LiAlH4) with iodine (I2) generates flammable H2 gas and lithium tetraiodoaluminate (LiAlI4) (Rittmeyer, P., U. Wietelmann. 2002. Hydrides. Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA. (Online)).
Reaction of NaH and Cl2 or F2 at ambient temperature is incandescent (J. W. Mellor, 1940. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 2, pp. 483. Longmans, Green and Co Ltd.).
Trimethylantimony reacts violently with halogens (Sidgwick, N. V., 1950, The Chemical Elements and their Compounds, Oxford, Oxford University Press, p. 777).
Barium acetylide incandesces with halogens above 122C (J. W. Mellor, 1946. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 5, pp. 862. Longmans, Green and Co Ltd.).
Potential Gas Byproducts
- Hydrogen (H2)
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