Reactivity Documentation
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
| mixed with |
Azo, Diazo, Azido, Hydrazine, and Azide Compounds |
Summary
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Aldehydes
- Ammonia
Details
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
is a reactive group.
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
mixed with
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
Hazard Predictions
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
AlH3 forms explosive products with tetrazoles (Fetter, N.R. et al. 1968. U.S. Patent 3396170).
Azides can be reduced to amines with metal hydrides (Cartolano, A. R. and Vedage, G. A. 2004. Amines by Reduction. Kirk-Othmer Encyclopedia of Chemical Technology. (Online)).
Complex metal hydrides can reduce hydrazides to aldehydes (Kohlpaintner, C., Schulte, M., Falbe, J., Lappe, P. and Weber, J. 2008. Aldehydes, Aliphatic. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).
Potential Gas Byproducts
- Aldehydes
- Ammonia (NH3)
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