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Hazard Predictions

• Flammable: Reaction products may be flammable
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)

Acidic salts may react exothermically with organometallics. These reactions are not expected to generate hazardous levels of heat.

Transition metal halides, some of which are acidic, react with iron pentacarbonyl to form transition-metal carbonyl compounds, which are often volatile and pyrophoric (Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Oxford: Butterworth-Heinemann., Vol. 1, pp. 610).