Reactivity Documentation
Acyl Halides, Sulfonyl Halides, and Chloroformates |
| mixed with |
Metals, Elemental and Powder, Active |
Summary
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Details
Reactivity Predictions (for each pair of reactive groups)
Acyl Halides, Sulfonyl Halides, and Chloroformates
Hazard Predictions
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Seleninyl chloride ignites on contact with antimony (Mellor, J. 1947. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 10, p. 906. Longmans, Green and Co Ltd.).
Zinc ignites on contact with seleninyl bromide (J. W. Mellor, 1947. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 10, pp. 912. Longmans, Green and Co Ltd.).
Iron catalytically decomposes acid halides, including benzyl chloroformate, isopropyl chloroformate, and ethyl oxalyl chloride (Anon., Loss Prevention Bulletin, 1975, (003), 2; Manual of Hazardous Chemical Reactions, NFPA 491M, Quincy (MA), National Fire Protection Association, 5th Ed., 1975, p. 223; Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Oxford: Butterworth-Heinemann. pp. 508).
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