Reactivity Documentation
Acyl Halides, Sulfonyl Halides, and Chloroformates |
| mixed with |
Azo, Diazo, Azido, Hydrazine, and Azide Compounds |
Summary
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Halogenated Amines
- Nitrogen
Details
Acyl Halides, Sulfonyl Halides, and Chloroformates
is a reactive group.
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
mixed with
Acyl Halides, Sulfonyl Halides, and Chloroformates
Acyl Halides, Sulfonyl Halides, and Chloroformates
Hazard Predictions
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
NaN3 forms explosive carbonyl azide with phosgene (Yajima, H. et al. 1970. Chemical Pharmaceutical Bulletin 50:12).
NaN3 forms an explosive solid with trifluoroacryloyl fluoride (Middleton, W.J. 1973. Journal of Organic Chemistry 38:3294).
NaN3 may form the impact-sensitive explosive 2,4,6-triazido-1,3,5-triazine when mixed with cyanuric chloride (Simmons, R.J. et al. 1982. Journal of the Chemical Society, Perkin Trans. 1:1824).
NaN3 reacts violently with benzoyl chloride in basic solution (Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 3064).
Potential Gas Byproducts
- Halogenated Amines
- Nitrogen (N2)
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