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Reactivity Documentation

Organometallics

mixed with

Sulfides, Inorganic

Summary

Details

Organometallics is a reactive group.
Sulfides, Inorganic is a reactive group.

Reactivity Predictions (for each pair of reactive groups)

Sulfides, Inorganic mixed with
Organometallics

Hazard Predictions

Anionic sulfur atoms bind strongly to atoms and ions of electron-rich metals such as copper, lead, mercury, nickel, iron, gold, and silver. Organometallic compounds containing these metals are likely to undergo exothermic ligand exchange reactions with inorganic sulfides (Housecroft, C. E.; Sharpe, A. G. Inorganic Chemistry, 2nd ed.; Pearson: Harlow (England), 2005, p. 445; Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 4th ed.; Wiley-Interscience: Hoboken (NJ), 2005; Mellor, J.W. 1967. Mellor's Modern Inorganic Chemistry, 6th Edition. John Wiley & Sons, Inc. pp. 666; Renner, H., et al. 2000. Gold, Gold Alloys, and Gold Compounds. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).