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Hazard Predictions

• Flammable: Reaction products may be flammable
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive

Cesium pentacarbonylvanadate (Cs3[V(CO)5]) reacts explosively with alcohols (Ellis, J. F. et al., J. Amer. Chem. Soc., 1981, 103, 6101).

Lower alcohols (1-4 carbon atoms) can protonate the cyclopentadienyl ligands of chromocene (dicyclopentadienylchromium) at 20 C to produce pyrophoric dialkoxychromium compounds and flammable cyclopentadiene (Votinsky, J. et al., Coll. Czech. Chem. Comm., 1979, 44, 82).

Potential Gas Byproducts

• Hydrocarbons