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Hazard Predictions

• Explosive: Reaction products may be explosive or sensitive to shock or friction
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
• Toxic: Reaction products may be toxic

Naphthalene explodes on contact with N2O5 (Mellor, J.W. 1940. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 8, p. 554. Longmans, Green and Co Ltd.).

Benzene can explode weakly on contact with nitryl perchlorate (Spinks, J.W.T. 1960. Chemical and Engineering News 38(15):5.).

Benzene reacts exothermically and may ignite or explode on contact with BrF5 (Mellor, J.W. 1956. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 2, Supp. 1, p. 172. Longmans, Green and Co Ltd.).

Benzene, and most other organic solvents, ignite on contact with BrF3 (Mellor, J.W. 1941. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 2, p. 113. Longmans, Green and Co Ltd.; Mellor, J.W. 1956. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 2, Supp. 1, p. 164-167. Longmans, Green and Co Ltd.).

Benzene ignites on contact with IF7 (Booth, H.S. et al. 1947. Chemical Reviews 41:428.).

Benzene ignites on contact with sodium peroxide (Na2O2) in water (Fire and Explosion Risks, von Schwartz, E., London, Griffin, 1918, p. 328.).

Benzene ignites on contact with CrO3 (Fawcett, H.H. 1959. Industrial and Engineering Chemistry Research 51(4):90A; Mikhailov, V. 1960. Chemical Abstracts 54:23331f; Mellor, J.W. 1943. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 11, p. 235. Longmans, Green and Co Ltd.).

Benzene will ignite on contact with dioxygenyl tetrafluoroborate at ambient temperatures (Goetschel, C.T. et al. 1969. Journal of the American Chemical Society 91:4706.).

Benzene and other aromatics form explosive ozonides on contact with ozone (Mellor, J.W. 1941. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Vol. 1, p. 911. Longmans, Green and Co Ltd.).

Benzene forms an explosive complex with silver perchlorate (Fundamentals of Fire and Explosion, AIChE Monograph Series No. 10, Stull, D. R., New York, American Institute of Chemical Engineers, 1977, p. 22.).

Benzene reacts violently with IF5 at slightly elevated temperatures (323K) (Ruff, O. et al. 1931. Z. Anorg. Chem. 201, 245.).

Potential Gas Byproducts

• Carbon Dioxide (CO2)