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Hazard Predictions

• Explosive: Reaction products may be explosive or sensitive to shock or friction
• Unstable when heated: Reaction products may be unstable above ambient temperatures
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive

Mixtures of CrO3 and hexamethylphosphoramide can explode if the CrO3 is crushed before use (Cardillo, G. et al. 1976. Synthesis 6:394-396.).

Interaction of dinitrogen tetraoxide and DMSO may be violent or explosive. (Buckley, A., J. Chem. Educ., 1965, 42, 674)

Mixtures of dimethylsulfoxide with some oxidizing salts such as aluminum perchlorate, sodium perchlorate, and iron (III) nitrate are powerful explosives. (Martin, D., Hauthal, H.G., Dimethylsulfoxid, Berlin, Akademie Verlag, 1971, p. 435)

IF5 (a strong halogenating reagent) reacts violently with dimethyl sulfoxide (Lawless, E.M. 1969. Chemical and Engineering News 47(13):8, 109.).

Potential Gas Byproducts

• Sulfur Dioxide (SO2)