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Hazard Predictions

• Corrosive: Reaction products may be corrosive
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Toxic: Reaction products may be toxic

Chlorine dioxide may react with some metal fluorides to liberate toxic fluorine gas (Masschelein, W. J. Chlorine Dioxide. Ann Arbor, MI: Ann Arbor Science Publishers Inc., 1979 pp. 40).

Hydrofluoric acid forms the powerful oxidizer HgF2 when it reacts with HgO; reactions involving a HF/HgO mixture and organic materials must be run at low temperature to avoid a runaway reaction (Ormston, J. 1944. School Science Review 26(98):32).

Lead (II) fluoride and silver fluoride react vigorously with fluorine gas. When aqueous solutions of silver fluoride react with fluorine, ozone-rich oxygen is released (Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Ed. Vol. 1. Oxford: Butterworth-Heinemann. pp. 1413).

Potential Gas Byproducts

• Halogen Gas (X2)