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Hazard Predictions

• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Toxic: Reaction products may be toxic

Chloroform reacts with hydrazine to liberate toxic HCl gas (Zollinger, Heinrich. Azo and Diazo Chemistry. New York: Interscience Publishers, Inc. 1961) Other haloforms may react similarly. Caution should be used before proceeding. Further research of comparable examples in the literature or very small scale, carefully controlled experiments may be needed to fully assess compatibility. The generation of gases may be rather slow, however confinement may lead to dangerous conditions.

Potential Gas Byproducts

• Hydrogen Halide (HX)