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Reactivity Documentation

Non-Redox-Active Inorganic Compounds

mixed with

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

Summary

Details

Reactivity Predictions (for each pair of reactive groups)

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters mixed with
Non-Redox-Active Inorganic Compounds

Hazard Predictions

Under normal conditions, the combination of esters and redox-inactive compounds do not create a hazardous condition. However, some reactions can occur under special conditions:

Thallium(III) oxide can catalyze the transfer of a sulfonate group from dimethyl sulfate to other organic molecules at elevated temperatures (McCormack, W. B. and Lawes, B. C. 2000. Sulfuric and Sulfurous Esters. Kirk-Othmer Encyclopedia of Chemical Technology. (Online)).

Titanium chloride and vanadium chloride react with dimethyl sulfate to form catalytically active compounds (for the polymerization of styrene or butadiene) (McCormack, W. B. and Lawes, B. C. 2000. Sulfuric and Sulfurous Esters. Kirk-Othmer Encyclopedia of Chemical Technology. (Online)).