Reactivity Documentation
Non-Redox-Active Inorganic Compounds |
mixed with |
Epoxides |
Summary
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Details
Reactivity Predictions (for each pair of reactive groups)
Non-Redox-Active Inorganic Compounds
Hazard Predictions
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Ethylene oxide can explosively polymerize on contact with iron oxides or aluminum oxides (Gupta, A.K. 1949. J. Soc. Chem. Ind. 68:179).
Iron oxides significantly lower the autoignition temperature of ethylene oxide, posing a fire hazard (Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Oxford: Butterworth-Heinemann. pp. 314).
Alkali metal halides and magnesium iodide can cause the ring opening of epoxides and epoxy alcohols (Landini, D., Maia, A. and Pinna, C. "Ring opening reactions of 1,2-epoxides catalyzed by complexes of polyether ligands with metal halides in low polarity solvents. Comparison with heterogeneous systems." ARKIVOC. [Online] 2004, Ann Arbor, Michigan: MPublishing, University of Michigan Library. http://hdl.handle.net/2027/spo.5550190.0005.317 (accessed Nov. 30, 2011)).