Reactivity Documentation
Nitrides, Phosphides, Carbides, and Silicides |
| mixed with |
Acyl Halides, Sulfonyl Halides, and Chloroformates |
Summary
- Corrosive: Reaction products may be corrosive
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Ammonia
Details
Nitrides, Phosphides, Carbides, and Silicides
is a reactive group.
Acyl Halides, Sulfonyl Halides, and Chloroformates
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Acyl Halides, Sulfonyl Halides, and Chloroformates
mixed with
Nitrides, Phosphides, Carbides, and Silicides
Nitrides, Phosphides, Carbides, and Silicides
Hazard Predictions
- Corrosive: Reaction products may be corrosive
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
Acyl halides undergo rapid nucleophilic attack by strong nucleophiles such as nitride ion (Loudon, Marc. 2002. Organic Chemistry. 4th ed. New York: Oxford University Press. p. 957-962). This reaction could produce amides and halide salts. If any water is present, it will also react with the acyl halide to generate carboxylic acid and HX gas, which can react with the remaining nitride to form ammonia.
Acetyl chloride reacts violently with strong bases (Pohanish, Richard P.; Greene, Stanley A. (2009). Wiley Guide to Chemical Incompatibilities (3rd Edition). John Wiley & Sons. p. 20).
Potential Gas Byproducts
- Ammonia (NH3)
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