Reactivity Documentation
Chlorosilanes |
| mixed with |
Nitrides, Phosphides, Carbides, and Silicides |
Summary
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Flammable: Reaction products may be flammable
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
-
May produce the following gases:
- Hydrogen
- Ammonia
Details
Chlorosilanes
is a reactive group.
Nitrides, Phosphides, Carbides, and Silicides
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Nitrides, Phosphides, Carbides, and Silicides
mixed with
Chlorosilanes
Chlorosilanes
Hazard Predictions
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Flammable: Reaction products may be flammable
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
A hazardous reaction is predicted between chlorosilanes and nitrides, with the possibility of an unstable product being generated. While no specific evidence was found for this interaction, chlorosilanes are known to react vigorously with strong bases.
Chlorosilanes can react with bases, releasing flammable H2 gas and possibly other gases (Arkles, B. 2000. Silicon Compounds, Silanes. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. (Online); Centre Européen des Silicones (CES), Safe Handling of Chlorosilanes, Chapter VIII, pg. 15. Found at http://www.silicones-safety.eu/files/Chlorosilanes Manual 22082003.pdf).
Potential Gas Byproducts
- Hydrogen (H2)
- Ammonia (NH3)
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