Reactivity Documentation
Halogenating Agents |
| mixed with |
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
-
May produce the following gases:
- Carbon Dioxide
- Sulfur Dioxide
Details
Halogenating Agents
is a reactive group.
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
mixed with
Halogenating Agents
Halogenating Agents
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
SOCl2 reacts with esters, such as ethyl acetate, forming toxic SO2 gas, catalyzed by Fe or Zn impurities (Spagnuolo, C.J. et al. 1992. Chemical and Engineering News 70(22):2.).
Reaction of ethyl acetate with IF7 is highly exothermic (Booth, H.S. et al. 1947. Chemical Reviews 41:428.).
Sulfates are incompatible with strong halogenating agents (Personal communication with chemical industry experts). Caution should be used before proceeding. Further research of comparable examples in the literature or very small scale, carefully controlled experiments may be needed to fully assess compatibility.
Potential Gas Byproducts
- Carbon Dioxide (CO2)
- Sulfur Dioxide (SO2)
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