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Hazard Predictions

• Corrosive: Reaction products may be corrosive
• Flammable: Reaction products may be flammable
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
• Toxic: Reaction products may be toxic

ClF3 forms toxic and highly flammable chlorodifluoroamine gas on contact with ammonium fluoride, even at low temperatures (Gardner, D.M. et al. 1936. Inorganic Chemistry, (2) p. 413).

ClF3 reacts violently with or may ignite on contact with iodide salts (Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Oxford: Butterworth-Heinemann. pp. 1237).

BrF3 reacts explosively with ammonium halide salts (Sharpe, A.G. 1948. Journal of the Chemical Society 2137).

Reaction between NaClO and ammonium salts can form explosive and toxic NCl3 gas (Anon. 1978. Loss Prevention Bulletin, Rugby, Institute of Chemical Engineers, (022) p. 116).

Potential Gas Byproducts

• Acid Fumes
• Chlorinated Amines
• Halogenated Amines