Reactivity Documentation
Halogenating Agents |
mixed with |
Nitrides, Phosphides, Carbides, and Silicides |
Summary
- Flammable: Reaction products may be flammable
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Details
Halogenating Agents
is a reactive group.
Nitrides, Phosphides, Carbides, and Silicides
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Nitrides, Phosphides, Carbides, and Silicides
mixed with
Halogenating Agents
Halogenating Agents
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Calcium carbide explodes violently if mixed with calcium hypochlorite and water (Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Oxford: Butterworth-Heinemann. pp. 1211.).
Silane burns on contact with Br2, Cl2, and covalent chlorides (Mellor, J.W. 1940. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Volume 6. pp. 220-221.).
Metal carbides ignite in cold F2 (Mellor, J.W. 1946. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Volume 5. pp. 849, 885, 890-891.).
Lithium nitride reacts violently and exothermically with SiF4 (Porritt, L.J. 1979. Chemistry in Britain 15:282-283.).