Reactivity Documentation
Amides and Imides |
mixed with |
Amines, Phosphines, and Pyridines |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Hydrogen Sulfide
- Ammonia
Details
Amides and Imides
is a reactive group.
Amines, Phosphines, and Pyridines
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Amides and Imides
mixed with
Amines, Phosphines, and Pyridines
Amines, Phosphines, and Pyridines
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Toxic: Reaction products may be toxic
Urea or N-alkylureas release NH3 gas when heated with primary amines, especially aromatic amines (Coffey, S., Ed. Rodd's Chemistry of carbon compounds; a modern comprehensive treatise, Second edition. New York: Elsevier Publishing Company, 1965. Vol. I, Part C, pp. 311-312).
Ethylamine and caprolactam (a cyclic amide) undergo a violent reaction when mixed (Pohanish, Richard P.; Greene, Stanley A. (2009). Wiley Guide to Chemical Incompatibilities (3rd Edition). John Wiley & Sons. p. 451-2.)
Thionamides may react with amines, anilines, hydrazine, and ammonium hydroxide to liberate toxic and flammable H2S gas (Smith, P. A. S., Open-Chain Nitrogen Compounds, Vol. I. New York: W. A. Benjamin, Inc., 1965, pp. 162).
Potential Gas Byproducts
- Ammonia (NH3)
- Hydrogen Sulfide (H2S)