Reactivity Documentation
Aryl Halides |
| mixed with |
Metals, Elemental and Powder, Active |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Acid Fumes
- Hydrogen Chloride
- Hydrogen Halide
Details
Aryl Halides
is a reactive group.
Metals, Elemental and Powder, Active
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Metals, Elemental and Powder, Active
mixed with
Aryl Halides
Aryl Halides
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
- Toxic: Reaction products may be toxic
Grignard reagents are produced by the reaction of alkyl and aryl bromides and chlorides with metallic magnesium. These products are pyrophoric and will react violently with water or air (Loudon, Marc. 2002. Organic Chemistry. 4th ed. New York: Oxford University Press. p. 334-336).
Halocarbons, including aryl halides, can react exothermically and sometimes explosively with aluminum. Reactions may evolve toxic HCl gas (Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Oxford: Butterworth-Heinemann. pp. 27-29).
Potential Gas Byproducts
- Acid Fumes
- Hydrogen Chloride (HCl)
- Hydrogen Halide (HX)
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